Free PDF , by E. Bright Wilson J. C. Decius
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, by E. Bright Wilson J. C. Decius
Free PDF , by E. Bright Wilson J. C. Decius
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Product details
File Size: 22347 KB
Print Length: 416 pages
Publisher: Dover Publications; Revised ed. edition (May 11, 2012)
Publication Date: April 13, 2012
Sold by: Amazon Digital Services LLC
Language: English
ASIN: B00B78IWZE
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Amazon Best Sellers Rank:
#719,430 Paid in Kindle Store (See Top 100 Paid in Kindle Store)
It seems that molecular vibrations is a topic which is treated on two levels these days: simple harmonic oscillators in undergraduate P-chem, and then maybe some calculations in a quantum chemistry program. Ended up in a research group where you need to know this stuff? Want to know what is going on "under the hood" of Gaussian? What's a normal coordinate? You mean I can determine frequencies without DFT? All your burning questions answered! The study of molecular vibrations is one of the pillars modern chemistry, and there is no substitute for this book.Yes, it is a little old fashioned (it has instructions for making analog integration circuits!), but really there is no better source. One thing though: set aside some time and really READ it. All the words. There are many gems scattered throughout, and if you just equation-hop you'll miss out on a lot. It has the same excellent price and nice (not fancy but hey, its not meant to sit on your shelf...read it!) printing you expect from Dover. They should get a Nobel prize for being the only non-criminal science publishers out there these days.
Good for spectroscopy students.
This is a classical book on the subject of molecular vibrations. People interested in molecular spectroscopy or Quantum Chemistry should read it. Excellent book!
great!
When I was a university student I learned about both vibrational spectroscopy and group theory applied to molecules from this book written in 1955 by Wilson, Decius, and Cross. Believe me, this is a classic reference that, although outdated in some place, it remains one of the best books ever written on the subject. The language used by the authors is of such an elegance that you will be surprised when reading this book. For example, on page 240 (ch.10) the authors describe the structure of benzene as follows: "The structure for benzene....is one in which all atoms are coplanar with the carbon atoms and the hydrogen atoms at the corners of concentric, regular hexagons." Five stars to this book and to Dover for keeping it alive!
In this one, Wilson writes definitively, math/scientifically, and with sincerity of purpose. Don't get confused by the word 'theory.' There's as much math in here as Born and Wolf's P of O. The only diffenrence is Wilson's is much more algebra-based. The mathematics (i.e. isomorphs) is 'taught', without breaking the flow, and is not assumed that you know the stuff already--- or can find it somewhere else. This book stands out because there is more science in here than names of scientists, and his references are for real. I would also say it was unique because books with titles like 'Molecular Vibrations' are usually skipped over for titles like 'mechanics' or 'quantum theory.' Spectroscopy was a major advancement in science, and it is good to see it skillfully treated with enlightening clarity.
This is the original work by E.B.Wilson where the G and F matrix formalism is presented. The G matrix, related to kinetic vibrational energy is built uppon the elements of the B matrix defined from "internal coordinates". Many quantum chemistry software packages use this exact methodology to build normal coordinates. For those working on Quantum Chem Molecular Orbital calculations, this book is a must.
It is probably the best book about molecular vibrations, cited in many other books.It treats complex arguments with rigour but at the same time it is able to explain them clearly.
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